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<br />fl <br />fl <br /> <br />fl <br />n <br /> <br />M Estimate ~ased on monitoring data or measurements for the substance. <br />Nate.:. These are "estimates" because even the best measurements have some <br />error associated with them. <br />C Estimate based on mass balance calculations if directly used to calculate mass. <br />E Estimate based on published emission factors. <br />o Estimate based on engineering calculations (using published mathematical formu- <br />las, e.g., evaporation rates) or best engineering judgment. <br /> <br />n <br /> <br />F. <br /> <br />Examples of Each Estimation Method <br /> <br />fl <br />~ ) <br /> <br />1. <br /> <br />Method M: Averages of measurements of Volatile Organic Compounds (VOCs) in water <br />sent to publicly owned treatment works (pOTW) multiplied by the total water discharge <br />as recorded by the public utility may be used to estimate outputs to the POTW of those <br />compounds. <br /> <br />~ 1 <br />t k <br /> <br />2. <br /> <br />Method C: To estimate releases of Chemical X to air from a process vent: <br /> <br />! 1 <br /> <br />'" t <br /> <br />Step 1. Draw a diagram, label all streams, and list input and output values. <br /> <br />, .. <br /> <br />.- J <br />\ <br />" J <br /> <br />VENT TO ATMOSPHERE - CHEMICAL X <br />OUTPUT 5 -- 500 lbs./yr. <br /> <br />MATERIALS ACCOUNI1NG <br />........................: BOUNDARY <br /> <br />PURCHASED <br />CHEMICAL X - <br />INPUT 4 <br />8,000 lbs./yr. <br /> <br /> <br />PROCESS <br /> <br />PRODUCT SHIPMENT- <br />OUTPUT 2 <br />6,000 lbs./yr. <br /> <br /> <br />SOLID WASTE- <br />OUTPUT 3 <br />1,5001bs./yr. <br /> <br />RECYCLED CHEMICAL X <br />2000 Ibs/yr <br /> <br />. . <br />.. . . . . . . . .. . .. . . . . . . . . . . . .. . . . . . . . . ... . . . . . . . . . . . . . . ... . . ... .. . .. .. .. .. .. <br /> <br />Consider a unit process that uses Chemical X to produce a product. In a year, 10,000 pounds of <br />Chemical X are used to produce 24,000 pounds of a product containing 25% (6,000 pounds) of <br />Chemical X by weight. The input consists of 8,000 pounds of purchased Chemical X and 2,000 <br />pounds that are collected from recycling. This process generates 10,000 pounds of solid waste <br />containing 15% (1,500 pounds) of Chemical X, and re-generates 2,000 pounds of Chemical X for <br />recycling. The only other unit process stream is a process vent, which emits an unknown amount <br />of Chemical X to the atmosphere. <br /> <br />16 <br />